Co2+ ions as probes of Al distribution in the framework of zeolites. ZSM-5 study

Abstract

The occurrence of “Al pairs” in the framework of ZSM-5 and their spatial distribution in zeolites was estimated by using exchanged Co²⁺ ions as probes for “Al pairs”. The visible spectra of Co²⁺ ions were employed to monitor the distribution of Co²⁺ ions, and thus “Al pairs”, among the individual cationic sites, i.e. local framework arrangements at defined positions in the zeolite channels. The effects of concentration of aluminum in the framework and conditions of zeolite synthesis on the presence of “Al pairs” and their spatial distribution in the ZSM-5 framework were investigated. It has been shown that the distribution of Al atoms in the framework is not controlled by statistic rules, but depends on the conditions of zeolite synthesis and aluminum concentration in the framework.