Issue 22, 2002
From the journal:

Chemical Communications

Crystallographic characterization of Isomer 2 of Er2@C82 and comparison with Isomer 1 of Er2@C82

Marilyn M. Olmstead,*a   Hon Man Lee,a   Steve Stevenson,b   Harry C. Dornc  and  Alan L. Balch*a  

* Corresponding authors

a Department of Chemistry, University of California, One Shields Avenue, Davis, CA, USA
E-mail: albalch@ucdavis.edu
Fax: +1 (530) 752 8995
Tel: +1 (530) 752 0941

b Luna Nanomaterials, 2851 Commerce Street, Blacksburg, VA 24060, USA
E-mail: stevensons@lunainnovations.com
Fax: +1 (540)-951-0760
Tel: +1 (540)-552-5128

c Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA
E-mail: hdorn@vt.edu
Fax: +1 (540)-231-3255
Tel: +1 (540)-231-5953

Abstract

The X-ray crystal structure of (Isomer 2 of Er2@C82)·NiII(OEP)·2(benzene) shows that the fullerene cage in Isomer 2 of Er2@C82 is the C3v isomer (82∶8) and that the erbium ions are distributed over 23 interior sites with occupancies ranging from 0.25 to 0.03.

Graphical abstract: Crystallographic characterization of Isomer 2 of Er2@C82 and comparison with Isomer 1 of Er2@C82

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Article information

DOI
https://doi.org/10.1039/B209270K
Article type
Communication
Submitted
20 Sep 2002
Accepted
01 Oct 2002
First published
21 Oct 2002

Chem. Commun., 2002, 2688-2689

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Crystallographic characterization of Isomer 2 of Er2@C82 and comparison with Isomer 1 of Er2@C82

M. M. Olmstead, H. M. Lee, S. Stevenson, H. C. Dorn and A. L. Balch, Chem. Commun., 2002, 2688 DOI: 10.1039/B209270K

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