Issue 24, 2002
From the journal:

Chemical Communications

Stable supramolecular dimer of self-complementary benzo-18-crown-6 with a pendant protonated amino arm†

Olga P. Kryatova,a   Sergey V. Kryatov,a   Richard J. Staplesb  and  Elena V. Rybak-Akimova*a  

* Corresponding authors

a Department of Chemistry, Tufts University, Medford, Massachusetts, USA
E-mail: elena.rybak-akimova@tufts.edu
Fax: 617-627-3443
Tel: 617-627-3413

b Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts, USA

Abstract

The novel 4′-(ammoniummethylene)benzo-18-crown-6 cation was synthesized as a hexafluorophosphate salt and found to exist as a cyclophane-like dimer in the solid state, gas phase and in acetonitrile solution.

Graphical abstract: Stable supramolecular dimer of self-complementary benzo-18-crown-6 with a pendant protonated amino arm

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Article information

DOI
https://doi.org/10.1039/B209235B
Article type
Communication
Submitted
19 Sep 2002
Accepted
23 Oct 2002
First published
08 Nov 2002

Chem. Commun., 2002, 3014-3015

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Stable supramolecular dimer of self-complementary benzo-18-crown-6 with a pendant protonated amino arm

O. P. Kryatova, S. V. Kryatov, R. J. Staples and E. V. Rybak-Akimova, Chem. Commun., 2002, 3014 DOI: 10.1039/B209235B

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