Issue 23, 2002
From the journal:

Chemical Communications

Variable coordination chemistry of the phospha(iii)guanidinate anion; application as a metal-functionalised phosphine ligand†

Martyn P. Coles*a  and  Peter B. Hitchcocka  

* Corresponding authors

a The Chemical Laboratories, University of Sussex, Falmer, Brighton, UK
E-mail: m.p.coles@sussex.ac.uk
Fax: 01273 677196
Tel: 01273 877339

Abstract

Structural investigation of Li-complexes of the phospha(III)guanidinate anion [Ph2PC{NiPr}2]− revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC{NiPr}2)AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported.

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Article information

DOI
https://doi.org/10.1039/B209026K
Article type
Communication
Submitted
17 Sep 2002
Accepted
09 Oct 2002
First published
24 Oct 2002

Chem. Commun., 2002, 2794-2795

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Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand

M. P. Coles and P. B. Hitchcock, Chem. Commun., 2002, 2794 DOI: 10.1039/B209026K

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