Issue 24, 2002
From the journal:

Chemical Communications

The first observation of four-electron reduction in [60]fullerene-metal cluster self-assembled monolayers (SAMs)†

Youn-Jaung Cho,a   Hyunjoon Song,a   Kwangyeol Lee,a   Kyuwon Kim,a   Juhyoun Kwak,a   Sehun Kima  and  Joon T. Park*a  

* Corresponding authors

a Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea
E-mail: jtpark@mail.kaist.ac.kr
Fax: +82 42 869 2810
Tel: +82 42 869 2826

Abstract

Self-assembled monolayers (SAMs) of a μ3-η2∶η2∶η2-C60 triosmium cluster complex Os3(CO)8(CN(CH2)3Si(OEt)3)(μ3-η2∶η2∶η2-C60) (2) on ITO or Au surface exhibit ideal, well-defined electrochemical responses and remarkable electrochemical stability being reducible up to tetraanionic species in their cyclic voltammograms.

Graphical abstract: The first observation of four-electron reduction in [60]fullerene-metal cluster self-assembled monolayers (SAMs)

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Article information

DOI
https://doi.org/10.1039/B209024D
Article type
Communication
Submitted
17 Sep 2002
Accepted
23 Oct 2002
First published
06 Nov 2002

Chem. Commun., 2002, 2966-2967

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The first observation of four-electron reduction in [60]fullerene-metal cluster self-assembled monolayers (SAMs)

Y. Cho, H. Song, K. Lee, K. Kim, J. Kwak, S. Kim and J. T. Park, Chem. Commun., 2002, 2966 DOI: 10.1039/B209024D

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