Issue 24, 2002
From the journal:

Chemical Communications

Ligand exchange reactions within the coordination sphere of a molybdenum η2(4e)-alkyne complex: the formation of an indole in a cascade reaction involving an alkyne and isonitrile ligands

John C. Jeffery,a   Michael Greena  and  Jason M. Lynam†*a  

* Corresponding authors

a School of Chemistry, University of Bristol, Bristol, UK
E-mail: jason.lynam@bris.ac.uk
Fax: +44(0)117 9251295
Tel: +44(0)117 9546325

Abstract

The exchange of phosphorus-containing ligands within the coordination sphere of molybdenum alkyne complexes is shown to be facile, a similar reaction with CNxyl (xyl = C6H3Me2-2,5) results in a remarkable coupling between the alkyne and three isonitrile ligands and C–H bond activation.

Graphical abstract: Ligand exchange reactions within the coordination sphere of a molybdenum η2(4e)-alkyne complex: the formation of an indole in a cascade reaction involving an alkyne and isonitrile ligands

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Article information

DOI
https://doi.org/10.1039/B208867C
Article type
Communication
Submitted
11 Sep 2002
Accepted
28 Oct 2002
First published
18 Nov 2002

Chem. Commun., 2002, 3056-3057

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Ligand exchange reactions within the coordination sphere of a molybdenum η2(4e)-alkyne complex: the formation of an indole in a cascade reaction involving an alkyne and isonitrile ligands

J. C. Jeffery, M. Green and J. M. Lynam, Chem. Commun., 2002, 3056 DOI: 10.1039/B208867C

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