Issue 20, 2002
From the journal:

Chemical Communications

Hammett analysis of a C–C hydrolase-catalysed reaction using synthetic 6-aryl-2-hydroxy-6-ketohexa-2,4-dienoic acid substrates

Damian M. Speare,a   Petra Olfa  and  Timothy D. H. Bugg*a  

* Corresponding authors

a Department of Chemistry, University of Warwick, Coventry, UK
E-mail: T.D.Bugg@warwick.ac.uk
Fax: 02476-524112
Tel: 02476-573018

Abstract

A Hammett plot (ρ = −0.71) has been measured for C–C hydrolase enzyme BphD from Pseudomonas LB400, using six 6-aryl-2-hydroxy-6-ketohexa-2,4-dienoic acids synthesised by a Heck coupling strategy.

Graphical abstract: Hammett analysis of a C–C hydrolase-catalysed reaction using synthetic 6-aryl-2-hydroxy-6-ketohexa-2,4-dienoic acid substrates

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Article information

DOI
https://doi.org/10.1039/B208168G
Article type
Communication
Submitted
20 Aug 2002
Accepted
06 Sep 2002
First published
20 Sep 2002

Chem. Commun., 2002, 2304-2305

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Hammett analysis of a C–C hydrolase-catalysed reaction using synthetic 6-aryl-2-hydroxy-6-ketohexa-2,4-dienoic acid substrates

D. M. Speare, P. Olf and T. D. H. Bugg, Chem. Commun., 2002, 2304 DOI: 10.1039/B208168G

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