Issue 21, 2002
From the journal:

Chemical Communications

Formation of novel diaza-metallacycles by insertion of tungsten(ii) aryloxides into aromatic diazine rings

Margaret R. Lentz,a   Phillip E. Fanwicka  and  Ian P. Rothwell*a  

* Corresponding authors

a Department of Chemistry 1393 Brown Building, Purdue University, West Lafayette, IN 47907-1393, USA
E-mail: rothwell@purdue.educ
Fax: +1 765-494-0239
Tel: +1 765-494-5473

Abstract

The tungsten(II) aryloxide [W(OC6HPh3-η6-C6H5)(OC6HPh4-2,3,5,6)(PMe3)] (1) (OC6HPh4-2,3,5,6 = 2,3,5,6-tetraphenylphenoxide) cleanly inserts into the aromatic diazine rings of pyridazine, benzo[c]cinnoline and phthalazine.

Graphical abstract: Formation of novel diaza-metallacycles by insertion of tungsten(ii) aryloxides into aromatic diazine rings

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Article information

DOI
https://doi.org/10.1039/B207805H
Article type
Communication
Submitted
09 Aug 2002
Accepted
13 Sep 2002
First published
27 Sep 2002

Chem. Commun., 2002, 2482-2483

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Formation of novel diaza-metallacycles by insertion of tungsten(II) aryloxides into aromatic diazine rings

M. R. Lentz, P. E. Fanwick and I. P. Rothwell, Chem. Commun., 2002, 2482 DOI: 10.1039/B207805H

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