Issue 19, 2002

First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

Abstract

A naturally occurring 1,1′-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be Sa-(−) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure.

Supplementary files

Article information

Article type
Communication
Submitted
01 Aug 2002
Accepted
23 Aug 2002
First published
06 Sep 2002

Chem. Commun., 2002, 2234-2235

First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

T. Hattori, Y. Shimazumi, O. Yamabe, E. Koshiishi and S. Miyano, Chem. Commun., 2002, 2234 DOI: 10.1039/B207517B

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