Issue 21, 2002
From the journal:

Chemical Communications

1-Phosphino-2-sulfenylferrocenes: efficient ligands in enantioselective palladium-catalyzed allylic substitutions and ring opening of 7-oxabenzonorbornadienes†

Julián Priego,a   Olga García Mancheño,a   Silvia Cabrera,a   Ramón Gómez Arrayás,a   Tomás Llamasa  and  Juan C. Carretero*a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain
E-mail: juancarlos.carretero@uam.es
Fax: +34 913973966
Tel: +34 913973925

Abstract

The readily available 1-phosphino-2-sulfenylferrocenes 1 provide very high enantioselectivities in Pd-catalyzed allylic substitution reactions and alkylative ring opening of 7-oxabenzonorbornadiene with dialkylzinc reagents.

Graphical abstract: 1-Phosphino-2-sulfenylferrocenes: efficient ligands in enantioselective palladium-catalyzed allylic substitutions and ring opening of 7-oxabenzonorbornadienes

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Article information

DOI
https://doi.org/10.1039/B207344G
Article type
Communication
Submitted
26 Jul 2002
Accepted
20 Sep 2002
First published
07 Oct 2002

Chem. Commun., 2002, 2512-2513

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1-Phosphino-2-sulfenylferrocenes: efficient ligands in enantioselective palladium-catalyzed allylic substitutions and ring opening of 7-oxabenzonorbornadienes

J. Priego, O. G. Mancheño, S. Cabrera, R. G. Arrayás, T. Llamas and J. C. Carretero, Chem. Commun., 2002, 2512 DOI: 10.1039/B207344G

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