Issue 20, 2002
From the journal:

Chemical Communications

Tris(1-4-η4-anthracene)niobate(1−), the first polyaromatic hydrocarbon complex of niobium†

William W. Brennessel,a   John E. Ellis,*a   Sergey N. Roush,a   Brian R. Strandberg,a   Oliver E. Woisetschlägera  and  Victor G. Young, Jr.a  

* Corresponding authors

a Department of Chemistry, University of Minnesota, Minneapolis, MN, USA
E-mail: ellis@chem.umn.edu
Fax: +1-612-626-7541

Abstract

The first tris(arene)niobium complex, [Nb(1-4-η4-anthracene)3]−, has been obtained by the sodium or potassium anthracene reduction of NbCl4(THF)2, structurally characterized by X-ray analysis and shown to undergo facile anthracene displacement reactions in the presence of excess CO, PF3, 1,3,5,7-cyclooctatetraene and P(OMe)3.

Graphical abstract: Tris(1-4-η4-anthracene)niobate(1−), the first polyaromatic hydrocarbon complex of niobium

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Article information

DOI
https://doi.org/10.1039/B207062F
Article type
Communication
Submitted
18 Jul 2002
Accepted
29 Aug 2002
First published
17 Sep 2002

Chem. Commun., 2002, 2356-2357

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Tris(1-4-η4-anthracene)niobate(1−), the first polyaromatic hydrocarbon complex of niobium

W. W. Brennessel, J. E. Ellis, S. N. Roush, B. R. Strandberg, O. E. Woisetschläger and V. G. Young, Chem. Commun., 2002, 2356 DOI: 10.1039/B207062F

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