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Issue 18, 2002
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Carbolithiation of aromatic rings: cyclohexadienes from N-aroyl-2,2,6,6-tetramethylpiperidines

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Abstract

Benzamides whose nitrogen atom is part of a 2,2,6,6-tetramethylpiperidine ring are dearomatised by alkyllithiums, which attack them regioselectively to yield, after electrophilic quench, substituted cyclohexadienes.

Graphical abstract: Carbolithiation of aromatic rings: cyclohexadienes from N-aroyl-2,2,6,6-tetramethylpiperidines

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Publication details

The article was received on 04 Jul 2002, accepted on 29 Jul 2002 and first published on 22 Aug 2002


Article type: Communication
DOI: 10.1039/B206479K
Chem. Commun., 2002, 2138-2139

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    Carbolithiation of aromatic rings: cyclohexadienes from N-aroyl-2,2,6,6-tetramethylpiperidines

    J. Clayden, Y. J. Y. Foricher and H. K. Lam, Chem. Commun., 2002, 2138
    DOI: 10.1039/B206479K

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