Issue 17, 2002
From the journal:

Chemical Communications

Synthesis of polycyclic compounds utilizing the nickel-catalysed alkynylstannylation of 1,2-dienes

Eiji Shirakawa,*a   Yoshiaki Nakao,b   Teruhisa Tsuchimotoa  and  Tamejiro Hiyama*b  

* Corresponding authors

a Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Asahidai, Tatsunokuchi, Ishikawa, Japan
E-mail: shira@jaist.ac.jp

b Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, Japan
E-mail: thiyama@npc05.kuic.kyoto-u.ac.jp

Abstract

Polycyclic compounds having linearly-fused six-membered rings can be readily prepared by various modes of cyclization from dienediynes, which were synthesized through the nickel-catalysed alkynylstannylation of 1,2-dienes followed by the palladium-catalysed oxidative homocoupling of the resulting alkenylstannanes.

Graphical abstract: Synthesis of polycyclic compounds utilizing the nickel-catalysed alkynylstannylation of 1,2-dienes

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Article information

DOI
https://doi.org/10.1039/B206240B
Article type
Communication
Submitted
28 Jun 2002
Accepted
24 Jul 2002
First published
08 Aug 2002

Chem. Commun., 2002, 1962-1963

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Synthesis of polycyclic compounds utilizing the nickel-catalysed alkynylstannylation of 1,2-dienes

E. Shirakawa, Y. Nakao, T. Tsuchimoto and T. Hiyama, Chem. Commun., 2002, 1962 DOI: 10.1039/B206240B

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