Issue 21, 2002
From the journal:

Chemical Communications

A novel, selective free-radical carbamoylation of heteroaromatic bases by Ce(iv) oxidation of formamide, catalysed by N-hydroxyphthalimide

Francesco Minisci,*a   Francesco Recupero,a   Carlo Punta,a   Cristian Gambarotti,a   Fabrizio Antonietti,a   Francesca Fontanab  and  Gian Franco Pedullic  

* Corresponding authors

a Dipartimento di Chimica, Materiali e Ingegneria Chimica ″G. Natta″, Politecnico di Milano, via Mancinelli 7, Milano, Italy
E-mail: francesco.minisci@polimi.it
Fax: +39 02 2399 3080
Tel: +39 02 2399 3030

b Dipartimento di Ingegneria, Università di Bergamo, viale Marconi 5, Dalmine BG, Italy
E-mail: fontana@unibg.it
Fax: +39 035 562779
Tel: +39 035 277322

c Dipartimento di Chimica Organica A.Mangini, Università di Bologna, via S. Donato 15, Bologna BO, Italy
E-mail: pedulli@kaiser.alma.unibo.it
Tel: +39 051 243218

Abstract

The Ce(IV)-NHPI system was used to generate a carbamoyl radical by oxidation of formamide; this nucleophilic radical has been successfully used in the carbamoylation of heteroaromatic bases.

Graphical abstract: A novel, selective free-radical carbamoylation of heteroaromatic bases by Ce(iv) oxidation of formamide, catalysed by N-hydroxyphthalimide

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Article information

DOI
https://doi.org/10.1039/B206192A
Article type
Communication
Submitted
27 Jun 2002
Accepted
18 Sep 2002
First published
08 Oct 2002

Chem. Commun., 2002, 2496-2497

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A novel, selective free-radical carbamoylation of heteroaromatic bases by Ce(IV) oxidation of formamide, catalysed by N-hydroxyphthalimide

F. Minisci, F. Recupero, C. Punta, C. Gambarotti, F. Antonietti, F. Fontana and G. F. Pedulli, Chem. Commun., 2002, 2496 DOI: 10.1039/B206192A

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