A new Zn(II) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites

Mitsuru Kondo; Makoto Miyazawa; Yasuhiko Irie; Reiko Shinagawa; Tomonori Horiba; Akira Nakamura; Tetsuyoshi Naito; Kenji Maeda; Shunji Utsuno; Fumio Uchida

doi:10.1039/B205866A

A new Zn(ii) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites†

Mitsuru Kondo,*^a Makoto Miyazawa,^a Yasuhiko Irie,^a Reiko Shinagawa,^a Tomonori Horiba,^a Akira Nakamura,^b Tetsuyoshi Naito,^c Kenji Maeda,^c Shunji Utsuno^c and Fumio Uchida^c

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* Corresponding authors

^a Department of Chemistry, Faculty of Science, Shizuoka University, 836 Ohya, Shizuoka, Japan
E-mail: scmkond@ipc.shizuoka.ac.jp

^b OM Research, 7-2-1308 Ohgimachi, Kita-ku, Osaka, Japan

^c Hautform Division, Fuji Chemical Co. Ltd, 1683-1880, Nakagaito, Nasubigawa, Nakatsugawa, Gifu, Japan

Abstract

A coordination polymer, [Zn(pyta)(OH)] (pyta = 4-pyridylthioacetate), was synthesized and structurally characterized; it is constructed by an alternating assembly of two types of homo-chiral helices, [Zn–OH] and [Zn-pyta], in which the sulfide moieties are fastened in the latter columns.

Chemical Communications

A new Zn(ii) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites†

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A new Zn(II) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites

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