Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2π partners: a novel and stereoselective route to functionalised bicyclo[2.2.2]octenones

Vishwakarma Singh; Shantanu Pal; Shaikh M. Mobin

doi:10.1039/B205475M

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Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2π partners: a novel and stereoselective route to functionalised bicyclo[2.2.2]octenones

Vishwakarma Singh,*^a Shantanu Pal^a and Shaikh M. Mobin^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology, Bombay, Mumbai, India
E-mail: vks@ether.chem.iitb.ac.in

^b National Single Crystal X-ray Diffraction Facility, Indian Institute of Technology, Bombay, Mumbai, India

Abstract

A novel route to functionalised bicyclo[2.2.2]octenones via π^4s + π^2s cycloaddition of cyclohexa-2,4-dienones with electron deficient 2π partners, and crystal structure of 1,7-dimethyl-5-hydroxy-5-chloromethyl-2-carboethoxy bicyclo[2.2.2]oct-7-ene-6-one, is reported.

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Supplementary files

Crystal structure data TXT (17K)

Article information

DOI: https://doi.org/10.1039/B205475M
Article type: Communication
Submitted: 06 Jun 2002
Accepted: 02 Aug 2002
First published: 15 Aug 2002

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Chem. Commun., 2002, 2050-2051

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Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2π partners: a novel and stereoselective route to functionalised bicyclo[2.2.2]octenones

V. Singh, S. Pal and S. M. Mobin, Chem. Commun., 2002, 2050 DOI: 10.1039/B205475M

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Chemical Communications

Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2π partners: a novel and stereoselective route to functionalised bicyclo[2.2.2]octenones

Abstract

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Article information

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Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2π partners: a novel and stereoselective route to functionalised bicyclo[2.2.2]octenones

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