Issue 16, 2002

DNA oxidation by peroxo-chromium(v) species: oxidation of guanosine to guanidinohydantoin

Abstract

Reactions of peroxo-chromium(V) complexes with DNA afforded mainly guanine oxidation yielding, a four-electron oxidation product, guanidinohydantoin, and exhibited extensive base labile strand scission.

Graphical abstract: DNA oxidation by peroxo-chromium(v) species: oxidation of guanosine to guanidinohydantoin

Article information

Article type
Communication
Submitted
05 Jun 2002
Accepted
24 Jun 2002
First published
11 Jul 2002

Chem. Commun., 2002, 1742-1743

DNA oxidation by peroxo-chromium(V) species: oxidation of guanosine to guanidinohydantoin

L. Joudah, S. Moghaddas and R. N. Bose, Chem. Commun., 2002, 1742 DOI: 10.1039/B205407H

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