Issue 20, 2002
From the journal:

Chemical Communications

Preferential solvation of an ILCT excited state in bis(terpyridine–phenylene–vinylene) Zn(ii) complexes

Xian-yong Wang,a   André Del Guerzoa  and  Russell H. Schmehl*a  

* Corresponding authors

a Tulane University, Chemistry Department, 6400 Freret St, New Orleans, Louisiana, USA
E-mail: russ@tulane.edu
Fax: +1 504 865 5596
Tel: +1 504 862 3266

Abstract

The excited state of terpyridine derivatives of phenylene–vinylene fragments chelating Zn(II) show a strong solvatochromism (up to 56 nm) upon preferential solvation by polar solvents of an intraligand charge transfer state.

Graphical abstract: Preferential solvation of an ILCT excited state in bis(terpyridine–phenylene–vinylene) Zn(ii) complexes

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Article information

DOI
https://doi.org/10.1039/B205042K
Article type
Communication
Submitted
23 May 2002
Accepted
20 Jun 2002
First published
16 Sep 2002

Chem. Commun., 2002, 2344-2345

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Preferential solvation of an ILCT excited state in bis(terpyridine–phenylene–vinylene) Zn(II) complexes

X. Wang, A. Del Guerzo and R. H. Schmehl, Chem. Commun., 2002, 2344 DOI: 10.1039/B205042K

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