Issue 16, 2002

Isolation of a new mixed valence Pt molecular oxide using phosphine as protecting group

Abstract

A novel tetranuclear mixed valence cationic Pt molecular oxide [{(Me3P)2Pt}3Pt(OH)6]4+ is obtained by reacting H2Pt(OH)6 and (Me3P)2Pt2+, whose NMR spectra suggest the existence of another species in solution that may serve as a starting point for further synthesis of Pt molecular oxides.

Supplementary files

Article information

Article type
Communication
Submitted
17 May 2002
Accepted
02 Jul 2002
First published
15 Jul 2002

Chem. Commun., 2002, 1770-1771

Isolation of a new mixed valence Pt molecular oxide using phosphine as protecting group

K. Noro, Y. Ozawa, M. Taguchi and A. Yagasaki, Chem. Commun., 2002, 1770 DOI: 10.1039/B204804C

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