Issue 17, 2002
From the journal:

Chemical Communications

Self-assembly luminescent heteroheptanuclear complexes with metal diphosphine and metal thiolate as components

Hong-Wu Xu,ab   Zhong-Ning Chen,*ad   Shoji Ishizaka,c   Noboru Kitamura*c  and  Ji-Gui Wu*b  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: czn@ms.fjirsm.ac.cn
Fax: 86 591 379 2346
Tel: 86 591 377 3944

b Department of Chemistry, Lanzhou University, Lanzhou, China

c Division of Chemistry, Graduate School of Science, Hokkaido University, Kita-ku, Sapporo, Japan

d State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, China

Abstract

Self-assembly between the building blocks [M2(μ-dppm)2(MeCN)2]2+ (M = Cu or Ag; dppm = bis(diphenylphosphino)methane) and M′(aet)2 (aet = 2-aminoethanethiolate) afforded luminescent heterohepta-nuclear complexes [Cu4M′3(μ-dppm)3(μ3-aet)4(μ-aet)2]4+ (M′ = Ni 1; Pd 2) or heterotrinuclear complexes [Ag2M′(μ-dppm)2(μ-aet)2]2+ (M′ = Ni 3, Pd 4).

Graphical abstract: Self-assembly luminescent heteroheptanuclear complexes with metal diphosphine and metal thiolate as components

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Article information

DOI
https://doi.org/10.1039/B204369F
Article type
Communication
Submitted
08 May 2002
Accepted
15 Jul 2002
First published
30 Jul 2002

Chem. Commun., 2002, 1934-1935

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Self-assembly luminescent heteroheptanuclear complexes with metal diphosphine and metal thiolate as components

H. Xu, Z. Chen, S. Ishizaka, N. Kitamura and J. Wu, Chem. Commun., 2002, 1934 DOI: 10.1039/B204369F

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