Issue 14, 2002

Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners

Abstract

Triphenylarsine catalyses the formation of epoxides from carbonyl compounds and tosylhydrazone salts. This convergent synthesis gives complete trans selectivity for all aldehyde and tosylhydrazone salt coupling partners.

Graphical abstract: Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners

Supplementary files

Article information

Article type
Communication
Submitted
03 May 2002
Accepted
27 May 2002
First published
19 Jun 2002

Chem. Commun., 2002, 1514-1515

Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners

V. K. Aggarwal, M. Patel and J. Studley, Chem. Commun., 2002, 1514 DOI: 10.1039/B204252E

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