Issue 14, 2002

A convergent, flexible synthesis of 1,3-dienes

Abstract

1,3-Dienes were prepared from 1,4-ketoxanthates, obtained by the radical addition reaction of an S-(2-oxoalkyl) xanthate to a terminal olefin, through the DBU induced thermal elimination of sulfur dioxide from the derived 2-sulfolenes.

Graphical abstract: A convergent, flexible synthesis of 1,3-dienes

Article information

Article type
Communication
Submitted
25 Apr 2002
Accepted
27 May 2002
First published
14 Jun 2002

Chem. Commun., 2002, 1532-1533

A convergent, flexible synthesis of 1,3-dienes

M. Lusinchi, T. V. Stanbury and S. Z. Zard, Chem. Commun., 2002, 1532 DOI: 10.1039/B203975C

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