Issue 14, 2002
From the journal:

Chemical Communications

Architectural formation of a conjugated bimetallic Pd(ii) complex via oxidative complexation and a tetracyclic Pd(ii) complex via self-assembling complexation†

Toshiyuki Moriuchi,a   Masayuki Kamikawa,a   Seiji Bandoha  and  Toshikazu Hirao*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, Osaka, Japan
E-mail: hirao@chem.eng.osaka-u.ac.jp

Abstract

The conjugated homobimetallic palladium(II) complex [(L1)Pd(qd)Pd(L1)] (qd = quinonediimine) was obtained in a one-pot reaction by the in-situ oxidative complexation of 1,4-phenylenediamine with the palladium(II) complex [(L1)Pd(MeCN)] (H2L1 = N,N′-bis(2-phenylethyl)-2,6-pyridinedicarboxamide) while in the absence of an additional ligand [(L1)Pd(MeCN)] was converted to the amide-bridged macrocyclic tetramer [Pd(L1)]4.

Graphical abstract: Architectural formation of a conjugated bimetallic Pd(ii) complex via oxidative complexation and a tetracyclic Pd(ii) complex via self-assembling complexation

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Article information

DOI
https://doi.org/10.1039/B203726M
Article type
Communication
Submitted
16 Apr 2002
Accepted
24 May 2002
First published
10 Jun 2002

Chem. Commun., 2002, 1476-1477

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Architectural formation of a conjugated bimetallic Pd(II) complex via oxidative complexation and a tetracyclic Pd(II) complex via self-assembling complexation

T. Moriuchi, M. Kamikawa, S. Bandoh and T. Hirao, Chem. Commun., 2002, 1476 DOI: 10.1039/B203726M

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