Issue 15, 2002
From the journal:

Chemical Communications

A novel system consisting of easily recyclable dendritic Ru-BINAP catalyst for asymmetric hydrogenation†

Guo-Jun Deng,a   Qing-Hua Fan,*a   Xiao-Min Chen,a   Dong-Sheng Liua  and  Albert S. C. Chan*b  

* Corresponding authors

a Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, P.R. China
E-mail: fanqh@infoc3.icas.ac.cn
Fax: 86-10-62559373

b Open Laboratory of Chirotechnology and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, P.R. China

Abstract

Dendritic Ru-BINAP catalysts functionalized with alkyl chain at the periphery together with organic binary solvent system that exhibited phase separation induced by addition of a little water have been employed for asymmetric hydrogenation, leading to high catalytic activity and enantioselectivity as well as facile catalyst recycling.

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Article information

DOI
https://doi.org/10.1039/B203117E
Article type
Communication
Submitted
28 Mar 2002
Accepted
06 Jun 2002
First published
20 Jun 2002

Chem. Commun., 2002, 1570-1571

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A novel system consisting of easily recyclable dendritic Ru-BINAP catalyst for asymmetric hydrogenation

G. Deng, Q. Fan, X. Chen, D. Liu and A. S. C. Chan, Chem. Commun., 2002, 1570 DOI: 10.1039/B203117E

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