Issue 12, 2002
From the journal:

Chemical Communications

Synthesis of a deca-lithium cage containing an [(RN)2As(μ-NR)As(NR)2]4− tetraanion; a homologue of group 15 trianions of the type [E(NR)3]3−†

Andrew D. Bond,a   Felipe García,a   Katja Jantos,a   Gavin T. Lawson,a   Mary McPartlina  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, Cambridge University, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk

b School of Chemistry, University of North London, London, UK

Abstract

The novel, deca-lithium cage [{mtaNHLi}{As2(Nmta)5}Li4·2thf]2 (1) (mtaN= 5-methylthiazolyl, C4H4N2S) contains an imido-bridged tetraanion [(mtaN)2As(μ-Nmta)As(Nmta)2]4−, which represents a new type of multifunctional imido group 15 ligand framework (homologous with group 15 anions of the type [As(NR)3]3−).

Graphical abstract: Synthesis of a deca-lithium cage containing an [(RN)2As(μ-NR)As(NR)2]4− tetraanion; a homologue of group 15 trianions of the type [E(NR)3]3−

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B202858A
Article type
Communication
Submitted
22 Mar 2002
Accepted
29 Apr 2002
First published
17 May 2002

Chem. Commun., 2002, 1276-1277

Permissions

Request permissions

Synthesis of a deca-lithium cage containing an [(RN)2As(μ-NR)As(NR)2]4− tetraanion; a homologue of group 15 trianions of the type [E(NR)3]3−

A. D. Bond, F. García, K. Jantos, G. T. Lawson, M. McPartlin and D. S. Wright, Chem. Commun., 2002, 1276 DOI: 10.1039/B202858A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements