Issue 15, 2002

A facile structural rearrangement to unprecedented μ266-bis(cyclopentadienylidene)ethene diruthenium complexes in the oxidation of 1,2-bis(ruthenocenyl)ethynes

Abstract

The two-electron oxidation of 1,2-bis(ruthenocenyl)ethynes and bis(1′,2′,3′,4′,5′-pentamethylruthenocenyl)ethynes, prepared from alkyne metathesis of the corresponding propynes, gave the unprecedented μ266-bis(cyclopentadienylidene)ethene diruthenium complexes.

Graphical abstract: A facile structural rearrangement to unprecedented μ2-η6:η6-bis(cyclopentadienylidene)ethene diruthenium complexes in the oxidation of 1,2-bis(ruthenocenyl)ethynes

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2002
Accepted
29 May 2002
First published
20 Jun 2002

Chem. Commun., 2002, 1574-1575

A facile structural rearrangement to unprecedented μ266-bis(cyclopentadienylidene)ethene diruthenium complexes in the oxidation of 1,2-bis(ruthenocenyl)ethynes

M. Sato and M. Watanabe, Chem. Commun., 2002, 1574 DOI: 10.1039/B202811P

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