Issue 15, 2002
From the journal:

Chemical Communications

The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙−, Cu2+ and Gd3+)

Augustin M. Madalan,a   Herbert W. Roesky,*b   Marius Andruh,*a   Mathias Noltemeyerb  and  Nicolae Stanicac  

* Corresponding authors

a University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory, Str. Dumbrava Rosie nr. 23, Bucharest, Romania
E-mail: marius.andruh@dnt.ro

b Institut für Anorganische Chemie der Universität, Tammannstr. 4, Göttingen, Germany
E-mail: hroesky@gwdg.de

c Institute of Physical Chemistry of the Romanian Academy, Coordination Chemistry Laboratory, Splaiul Independentei, nr. 202A, Bucharest, Romania

Abstract

A novel heterospin system, [{CuL}2Gd(TCNQ)2]·TCNQ·CH3OH·2CH3CN, is obtained by reacting the mononuclear complex, [CuL], with gadolinium(III) nitrate, followed by the substitution of the nitrato ions with anionic organic radicals.

Graphical abstract: The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙−, Cu2+ and Gd3+)

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Article information

DOI
https://doi.org/10.1039/B202628G
Article type
Communication
Submitted
14 Mar 2002
Accepted
07 Jun 2002
First published
28 Jun 2002

Chem. Commun., 2002, 1638-1639

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The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙−, Cu2+ and Gd3+)

A. M. Madalan, H. W. Roesky, M. Andruh, M. Noltemeyer and N. Stanica, Chem. Commun., 2002, 1638 DOI: 10.1039/B202628G

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