Issue 10, 2002
From the journal:

Chemical Communications

Synthesis of novel BINOL-derived chiral bisphosphorus ligands and their application in catalytic asymmetric hydrogenation

Yong-Gui Zhoua  and  Xumu Zhang*a  

* Corresponding authors

a Department of Chemistry, The Pennsylvania State University, University Park, PA, USA
E-mail: xumu@chem.psu.edu

Abstract

Some novel ortho-substituted BINOL-derived bisphosphorus ligands (o-BINAPO and o-NAPHOS) were synthesis from readily available (S)-BINOL; these ligands showed excellent enantioselectivities (up to 99% ee) in Rh(I)-catalyzed asymmetric hydrogenation of functionalized olefins.

Graphical abstract: Synthesis of novel BINOL-derived chiral bisphosphorus ligands and their application in catalytic asymmetric hydrogenation

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Article information

DOI
https://doi.org/10.1039/B201976K
Article type
Communication
Submitted
19 Feb 2002
Accepted
01 Apr 2002
First published
19 Apr 2002

Chem. Commun., 2002, 1124-1125

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Synthesis of novel BINOL-derived chiral bisphosphorus ligands and their application in catalytic asymmetric hydrogenation

Y. Zhou and X. Zhang, Chem. Commun., 2002, 1124 DOI: 10.1039/B201976K

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