Palladium dimethylsilanedithiolato complex: a precursor for Ti–Pd and Ti–Pd2 heterometallic complexes

Takashi Komuro; Tsukasa Matsuo; Hiroyuki Kawaguchi; Kazuyuki Tatsumi

doi:10.1039/B201702D

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Palladium dimethylsilanedithiolato complex: a precursor for Ti–Pd and Ti–Pd₂ heterometallic complexes†

Takashi Komuro,^a Tsukasa Matsuo,^b Hiroyuki Kawaguchi*^b and Kazuyuki Tatsumi^a

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* Corresponding authors

^a Research Center for Materials Science, and, Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Japan

^b Coordination Chemistry Laboratories, Institute for Molecular Science, Myodaiji, Okazaki, Japan
E-mail: hkawa@ims.ac.jp

Abstract

The silanedithiolato complex Pd(S₂SiMe₂)(PEt₃)₂1 reacted with (C₅H₅)TiCl₃ and TiCl₄(thf)₂ to produce the heterometallic clusters (C₅H₅)TiCl(μ-S)₂Pd(PEt₃)₂2 and TiCl₂(S)(μ-S)₂Pd₂(PEt₃)₄3 along with silicon–sulfur bond cleavage, respectively.

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Article information

DOI: https://doi.org/10.1039/B201702D
Article type: Communication
Submitted: 15 Feb 2002
Accepted: 21 Mar 2002
First published: 08 Apr 2002

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Chem. Commun., 2002, 988-989

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Palladium dimethylsilanedithiolato complex: a precursor for Ti–Pd and Ti–Pd₂ heterometallic complexes

T. Komuro, T. Matsuo, H. Kawaguchi and K. Tatsumi, Chem. Commun., 2002, 988 DOI: 10.1039/B201702D

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