Issue 11, 2002
From the journal:

Chemical Communications

First successful reaction of a silyl anion with hafnium tetrachloride

Dieter Frank,a   Judith Baumgartnera  and  Christoph Marschner*a  

* Corresponding authors

a Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, Graz, Austria
E-mail: marschner@anorg.tu-graz.ac.at

Abstract

Hafnium tetrachloride reacts with the tris(trimethylsilyl)silyl potassium tmen adduct (1) to form a [tris(trimethylsilyl)silyl]trichlorohafnium tmen complex (2); reaction of 2 with 2,6-dimethylphenylisonitrile leads to insertion into the silicon hafnium bond (4).

Graphical abstract: First successful reaction of a silyl anion with hafnium tetrachloride

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Article information

DOI
https://doi.org/10.1039/B201508K
Article type
Communication
Submitted
11 Feb 2002
Accepted
15 Apr 2002
First published
30 Apr 2002

Chem. Commun., 2002, 1190-1191

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First successful reaction of a silyl anion with hafnium tetrachloride

D. Frank, J. Baumgartner and C. Marschner, Chem. Commun., 2002, 1190 DOI: 10.1039/B201508K

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