Issue 9, 2002
From the journal:

Chemical Communications

18O incorporation in the oxidation of N-methylcarbazole by lignin peroxidase and a model compound: a mechanistic insight into the oxidative N-demethylation of aromatic tertiary amines

Enrico Baciocchi,*a   Maria Francesca Gerinib  and  Andrea Lapib  

* Corresponding authors

a Dipartimento di Chimica, Università “La Sapienza”, P.le A. Moro 5, Roma, Italy
E-mail: enrico.baciocchi@uniroma1.it

b Dipartimento di Chimica and Centro CNR di Studio sui Meccanismi di Reazione, Università “La Sapienza”, P.le A. Moro 5, Roma, Italy

Abstract

Using 18O labelled reactants and/or solvent, the origin of the oxygen in the products of the oxidation of N-methylcarbazole by H2O2 catalysed by lignin peroxidase and a model compound has been determined, so getting important information about the mechanism of the oxidative N-demethylation of aromatic tertiary amines.

Graphical abstract: 18O incorporation in the oxidation of N-methylcarbazole by lignin peroxidase and a model compound: a mechanistic insight into the oxidative N-demethylation of aromatic tertiary amines

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Article information

DOI
https://doi.org/10.1039/B201492K
Article type
Communication
Submitted
12 Feb 2002
Accepted
18 Mar 2002
First published
02 Apr 2002

Chem. Commun., 2002, 946-947

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18O incorporation in the oxidation of N-methylcarbazole by lignin peroxidase and a model compound: a mechanistic insight into the oxidative N-demethylation of aromatic tertiary amines

E. Baciocchi, M. F. Gerini and A. Lapi, Chem. Commun., 2002, 946 DOI: 10.1039/B201492K

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