Issue 7, 2002
From the journal:

Chemical Communications

Fast and unprecedented chemoselective hydroformylation of acrylates with a fluoropolymer ligand in supercritical CO2

Yulai Hu,a   Weiping Chen,a   Anna M. Banet Osuna,a   Jon A. Iggoa  and  Jianliang Xiao*a  

* Corresponding authors

a Leverhulme Centre for Innovative Catalysis, Department of Chemistry, University of Liverpool, Liverpool, UK
E-mail: j.xiao@liv.ac.uk
Fax: (+44) 151 7943589
Tel: (+44) 151 7942979

Abstract

A fluorous polymeric phosphine, when combined with supercritical CO2 (scCO2) and rhodium, effects fast and highly chemoselective hydroformylation of acrylates, one of the least reactive olefins in hydroformylation reactions.

Graphical abstract: Fast and unprecedented chemoselective hydroformylation of acrylates with a fluoropolymer ligand in supercritical CO2

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Article information

DOI
https://doi.org/10.1039/B201166B
Article type
Communication
Submitted
31 Jan 2002
Accepted
04 Mar 2002
First published
13 Mar 2002

Chem. Commun., 2002, 788-789

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Fast and unprecedented chemoselective hydroformylation of acrylates with a fluoropolymer ligand in supercritical CO2

Y. Hu, W. Chen, A. M. B. Osuna, J. A. Iggo and J. Xiao, Chem. Commun., 2002, 788 DOI: 10.1039/B201166B

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