Issue 7, 2002
From the journal:

Chemical Communications

Polynitrile-bridged two-dimensional crystal: Eu(iii) complex with strong fluorescence emission and NLO property

Jing-min Shi,*a   Wen Xu,a   Qing-yun Liu,a   Feng-ling Liu,a   Zhen-li Huang,b   Hong Lei,b   Wen-tao Yuc  and  Qi Fangc  

* Corresponding authors

a Department of Chemistry, Shandong Normal University, Jinan, P.R. China
E-mail: shijingmin@sina.com

b Institute of Laser and Spectroscopy, Zhongshan University, Guangzhou, P.R. China

c Institute of Crystal Materials, Shandong University, Jinan, P.R. China

Abstract

The first polynitrile coordinated lanthanide complex {[Eu(cda)3(H2O)3]·H2O}∞ (cda = carbamyldicyanomethanide anion) has been synthesized and the two-dimensional structure coordination polymer exhibits strong fluorescence emission and strong powder second harmonic generation efficiency (16.8 times that of urea).

Graphical abstract: Polynitrile-bridged two-dimensional crystal: Eu(iii) complex with strong fluorescence emission and NLO property

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Article information

DOI
https://doi.org/10.1039/B200894G
Article type
Communication
Submitted
23 Jan 2002
Accepted
28 Feb 2002
First published
12 Mar 2002

Chem. Commun., 2002, 756-757

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Polynitrile-bridged two-dimensional crystal: Eu(III) complex with strong fluorescence emission and NLO property

J. Shi, W. Xu, Q. Liu, F. Liu, Z. Huang, H. Lei, W. Yu and Q. Fang, Chem. Commun., 2002, 756 DOI: 10.1039/B200894G

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