Issue 8, 2002

Tandem intermolecular Suzuki coupling/intramolecular vinyl triflate–arene coupling

Abstract

Treatment of a benzyl substituted meso-ditriflate with boronic acids in the presence of palladium acetate, triphenylphosphine and caesium fluoride results in intermolecular Suzuki coupling followed by vinyl triflate–arene cyclisation to provide, in high yields, single regioisomers of tricyclic-carbocycles.

Graphical abstract: Tandem intermolecular Suzuki coupling/intramolecular vinyl triflate–arene coupling

Supplementary files

Article information

Article type
Communication
Submitted
21 Jan 2002
Accepted
07 Mar 2002
First published
20 Mar 2002

Chem. Commun., 2002, 832-833

Tandem intermolecular Suzuki coupling/intramolecular vinyl triflate–arene coupling

M. C. Willis, C. K. Claverie and M. F. Mahon, Chem. Commun., 2002, 832 DOI: 10.1039/B200692H

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