Revealing the photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+: a picosecond time-resolved IR study

Joanne Dyer; David C. Grills; Pavel Matousek; Anthony W. Parker; Michael Towrie; Julia A. Weinstein; Michael W. George

doi:10.1039/B200586G

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Revealing the photophysics of fac-[(dppz-12-NO₂)Re(CO)₃(4-Me₂Npy)]⁺: a picosecond time-resolved IR study†

Joanne Dyer,^a David C. Grills,^a Pavel Matousek,^b Anthony W. Parker,^b Michael Towrie,^b Julia A. Weinstein^a and Michael W. George*^a

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* Corresponding authors

^a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: mike.george@nottingham.ac.uk

^b Central Laser Facility, Chilton, Didcot, Oxon, UK

Abstract

The photophysics of fac-[(dppz-12-NO₂)Re(CO)₃(4-Me₂Npy)]⁺ in CH₃CN have been investigated using picosecond time-resolved IR (ps-TRIR) spectroscopy, to reveal the first example of a Re(I)–dppz complex with a charge separated lowest-lying excited state.

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Supplementary files

Synthetic procedures, product characterization and brief description of the ps-TRIR experiments DOC (30K)

Article information

DOI: https://doi.org/10.1039/B200586G
Article type: Communication
Submitted: 18 Jan 2002
Accepted: 12 Mar 2002
First published: 22 Mar 2002

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Chem. Commun., 2002, 872-873

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Revealing the photophysics of fac-[(dppz-12-NO₂)Re(CO)₃(4-Me₂Npy)]⁺: a picosecond time-resolved IR study

J. Dyer, D. C. Grills, P. Matousek, A. W. Parker, M. Towrie, J. A. Weinstein and M. W. George, Chem. Commun., 2002, 872 DOI: 10.1039/B200586G

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