Issue 8, 2002

Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(ii) and palladium(ii) azuliporphyrins

Abstract

Brief treatment of azuliporphyrins 5 with nickel(II) or palladium(II) acetate in refluxing DMF afforded excellent yields of the related chelates; these novel organometallic compounds retain cross-conjugated borderline aromatic structures as judged by UV-Vis and NMR spectroscopy, and X-ray crystallography.

Graphical abstract: Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(ii) and palladium(ii) azuliporphyrins

Supplementary files

Article information

Article type
Communication
Submitted
27 Dec 2001
Accepted
12 Mar 2002
First published
25 Mar 2002

Chem. Commun., 2002, 894-895

Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins

S. R. Graham, G. M. Ferrence and T. D. Lash, Chem. Commun., 2002, 894 DOI: 10.1039/B200131B

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