Issue 6, 2002

Formal syntheses of heliannuols A and D, allelochemicals from Helianthus Annus

Abstract

A synthesis of heliannuol A 1 is described involving hydrogenolysis of the cyclopropane fused benzoxepane compound 23 to generate the benzoxocane ring system of 1 and a fragmentation of methyl ether 25 furnished 4-methoxycurcuphenol 29, an advanced intermediate to heliannuol D 4.

Graphical abstract: Formal syntheses of heliannuols A and D, allelochemicals from Helianthus Annus

Article information

Article type
Communication
Submitted
03 Jan 2002
Accepted
08 Feb 2002
First published
22 Feb 2002

Chem. Commun., 2002, 634-635

Formal syntheses of heliannuols A and D, allelochemicals from Helianthus Annus

K. Tuhina, D. R. Bhowmik and R. V. Venkateswaran, Chem. Commun., 2002, 634 DOI: 10.1039/B200103A

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