Issue 6, 2002
From the journal:

Chemical Communications

Transmetallation of β-allenyl silanes: efficient synthesis of dienyl chlorostannanes and chlorostibines†

Mokhtar Lahrech,a   Jérôme Thibonnet,b   Salih Hacini,a   Maurice Santelli*b  and  Jean-Luc Parrain*b  

* Corresponding authors

a Laboratoire de Synthèse Organique, Université d′Oran Es-Senia, Oran, Algérie

b Laboratoire de Synthèse Organique associé au CNRS, Faculté des Sciences de Saint Jérôme, Avenue Escadrille Normandie-Niemen, Marseille Cedex 20, France
E-mail: jl.parrain@univ.u-3mrs.fr
Fax: 33 4 91 98 38 65
Tel: 33 4 91 28 89 14

Abstract

The reaction of 1-trimethylsilylbuta-2,3-diene with tin tetrachloride, antimony trichloride or antimony pentachloride gave the corresponding buta-1,3-dien-2-yl halostannane or stibine derivatives; this ligand exchange was extended to other β-allenylsilanes.

Graphical abstract: Transmetallation of β-allenyl silanes: efficient synthesis of dienyl chlorostannanes and chlorostibines

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Article information

DOI
https://doi.org/10.1039/B111580B
Article type
Communication
Submitted
19 Dec 2001
Accepted
30 Jan 2002
First published
25 Feb 2002

Chem. Commun., 2002, 644-645

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Transmetallation of β-allenyl silanes: efficient synthesis of dienyl chlorostannanes and chlorostibines

M. Lahrech, J. Thibonnet, S. Hacini, M. Santelli and J. Parrain, Chem. Commun., 2002, 644 DOI: 10.1039/B111580B

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