Issue 4, 2002
From the journal:

Chemical Communications

Molybdenum alkynyls as alkynyl transfer reagents†

Julio Pérez,*a   Lucía Riera,a   Víctor Riera,a   Santiago García-Granda,b   Esther García-Rodríguezb  and  Daniel Miguelc  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica/I.U.Q.O.E.M, Facultad de Química, Universidad de Oviedo-C.S.I.C, Oviedo, Spain
E-mail: japm@sauron.quimica.uniovi.es
Fax: +34985103446

b Departamento de Química Física y Analítica, Facultad de Química, Universidad de Oviedo-C.S.I.C, Oviedo, Spain

c Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Valladolid, Spain

Abstract

Molybdenum alkynyl complexes [Mo(C[triple bond, length as m-dash]CR)(η3-allyl)(CO)2(phen)] feature long Mo–Calkynyl bond distances and propensity to undergo the cleavage of these bonds, a property that allowed their use as acetylide transfer reagents.

Graphical abstract: Molybdenum alkynyls as alkynyl transfer reagents

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Article information

DOI
https://doi.org/10.1039/B110864F
Article type
Communication
Submitted
28 Nov 2001
Accepted
18 Dec 2001
First published
30 Jan 2002

Chem. Commun., 2002, 384-385

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Molybdenum alkynyls as alkynyl transfer reagents

J. Pérez, L. Riera, V. Riera, S. García-Granda, E. García-Rodríguez and D. Miguel, Chem. Commun., 2002, 384 DOI: 10.1039/B110864F

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