Issue 5, 2002
From the journal:

Chemical Communications

A new supramolecular assembly obtained from the combination of silver(i) cations with a thiophosphorylated cavitand

Brigitte Bibal,a   Bernard Tinant,b   Jean-Paul Declercqb  and  Jean-Pierre Dutasta*a  

* Corresponding authors

a Stéréochimie et Interactions Moléculaires, École Normale Supérieure de Lyon, UMR CNRS n° 5532, 46 Allée d’Italie, Lyon Cedex 07, France
E-mail: dutasta@ens-lyon.fr

b Laboratoire de Chimie-physique et de Cristallographie, Université Catholique de Louvain, Place Louis Pasteur 1, Louvain-La-Neuve, Belgium

Abstract

The new tetra-thiophosphonatocavitand 1 in its iiii configuration extracts quantitatively Ag+ ions from aqueous solutions; the tetranuclear complex [12·Ag4Pic4] was selectively formed and characterized in the solid state by X-ray diffraction which revealed the formation of a new dimeric assembly through Ag+ coordination.

Graphical abstract: A new supramolecular assembly obtained from the combination of silver(i) cations with a thiophosphorylated cavitand

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Article information

DOI
https://doi.org/10.1039/B110698H
Article type
Communication
Submitted
22 Nov 2001
Accepted
25 Jan 2002
First published
11 Feb 2002

Chem. Commun., 2002, 432-433

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A new supramolecular assembly obtained from the combination of silver(I) cations with a thiophosphorylated cavitand

B. Bibal, B. Tinant, J. Declercq and J. Dutasta, Chem. Commun., 2002, 432 DOI: 10.1039/B110698H

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