Issue 5, 2002

Mixed-anion complexes with a bipyrazolyl ligand. A new entry to a realm of three-dimensional five-connected coordination topologies

Abstract

Cross-linking of corrugated square grid coordination layers by anionic bridging groups generates five-connected coordination networks; the 3D topologies of mixed-anion cobalt(II) and nickel(II) complexes with a tetramethyl-substituted 4,4′-bipyrazolyl ligand are supported by μ-SO42− functions and exist as neutral or cationic five-connected arrays involving additional terminal (NCS) or non-coordinated (NO3, ClO4) groups.

Graphical abstract: Mixed-anion complexes with a bipyrazolyl ligand. A new entry to a realm of three-dimensional five-connected coordination topologies

Supplementary files

Article information

Article type
Communication
Submitted
19 Nov 2001
Accepted
25 Jan 2002
First published
13 Feb 2002

Chem. Commun., 2002, 436-437

Mixed-anion complexes with a bipyrazolyl ligand. A new entry to a realm of three-dimensional five-connected coordination topologies

V. V. Ponomarova, V. V. Komarchuk, I. Boldog, A. N. Chernega, J. Sieler and K. V. Domasevitch, Chem. Commun., 2002, 436 DOI: 10.1039/B110599J

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