This article reports the first work on the use of silica supported dendritic chiral auxiliaries for the enantioselective addition of diethylzinc to benzaldehyde: the control of dendrimer propagation on the silica surface is of prime importance to obtain enhanced conversion, selectivity, and enantioselectivity.
Y. Chung and H. Rhee, Chem. Commun., 2002, 238 DOI: 10.1039/B110331H
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