Issue 13, 2002

Electronic coupling in 6,6″-donor-substituted terpyridines: tuning of the mixed valence state by proton and metal ion complexation

Abstract

6,6″-Terpyridyl-bishydroquinone conjugates are synthesised by Pd-catalyzed cross-coupling and their conformational switching, triggered by protons, zinc(II) or cobalt(II), is studied by cyclovoltammetry and in situ UV/Vis/NIR and FT-IR spectroelectrochemistry.

Graphical abstract: Electronic coupling in 6,6″-donor-substituted terpyridines: tuning of the mixed valence state by proton and metal ion complexation

Supplementary files

Article information

Article type
Communication
Submitted
12 Nov 2001
Accepted
30 Apr 2002
First published
22 May 2002

Chem. Commun., 2002, 1338-1339

Electronic coupling in 6,6″-donor-substituted terpyridines: tuning of the mixed valence state by proton and metal ion complexation

M. Büschel, M. Helldobler and J. Daub, Chem. Commun., 2002, 1338 DOI: 10.1039/B110289C

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