Issue 1, 2002

Synthesis, crystal and molecular structure of [Sn(η4-P2C2But2)]: the first non transition metal 1,3-diphosphacyclobutadienyl compound

Abstract

Treatment of [Zr(η5-C5H5)2(PCBut)2] with SnCl2 led to the novel monomeric (1,3-diphosphacyclobutadienyl)tin(II) half sandwich complex [Sn(η4-P2C2But2)] which has been characterised by multinuclear NMR spectroscopy and in the solid state by a single crystal X-ray diffraction study.

Supplementary files

Article information

Article type
Communication
Submitted
08 Nov 2001
Accepted
03 Dec 2001
First published
21 Dec 2001

Chem. Commun., 2002, 86-87

Synthesis, crystal and molecular structure of [Sn(η4-P2C2But2)]: the first non transition metal 1,3-diphosphacyclobutadienyl compound

M. D. Francis and P. B. Hitchcock, Chem. Commun., 2002, 86 DOI: 10.1039/B110228C

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