Issue 4, 2002
From the journal:

Chemical Communications

Hexakis(2-pyridyl)- and hexakis(3-pyridyl)[3]radialene: novel, water-soluble [3]radialenes with potential utility for supramolecular chemistry

Kouzou Matsumoto,a   Yukako Harada,a   Takeshi Kawasea  and  Masaji Oda*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan
E-mail: moda@chem.sci.osaka-u.ac.jp
Fax: +81 6 6850 5387
Tel: +81 6 6850 5385

Abstract

The titled [3]radialenes are the first, water-soluble hexaaryl[3]radialenes with considerably high electron affinity, their alkali metal reduction giving rise to anion-radicals and dianions stepwise as fairly stable species in degassed tetrahydrofuran.

Graphical abstract: Hexakis(2-pyridyl)- and hexakis(3-pyridyl)[3]radialene: novel, water-soluble [3]radialenes with potential utility for supramolecular chemistry

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Article information

DOI
https://doi.org/10.1039/B110058K
Article type
Communication
Submitted
05 Nov 2001
Accepted
04 Jan 2002
First published
18 Jan 2002

Chem. Commun., 2002, 324-325

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Hexakis(2-pyridyl)- and hexakis(3-pyridyl)[3]radialene: novel, water-soluble [3]radialenes with potential utility for supramolecular chemistry

K. Matsumoto, Y. Harada, T. Kawase and M. Oda, Chem. Commun., 2002, 324 DOI: 10.1039/B110058K

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