Issue 5, 2002

Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

Abstract

Novel monodentate phosphorus ligands containing the 1,1′-spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).

Graphical abstract: Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

Article information

Article type
Communication
Submitted
02 Nov 2001
Accepted
22 Jan 2002
First published
07 Feb 2002

Chem. Commun., 2002, 480-481

Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

Y. Fu, J. Xie, A. Hu, H. Zhou, L. Wang and Q. Zhou, Chem. Commun., 2002, 480 DOI: 10.1039/B109827F

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