Facile synthesis of ketones from 1,1-disilylethenes via oxidation of gem-disilylalkanes
Abstract
The oxidation of gem-disilylalkanes, which can be derived from 1,1-disilylethene, alkyllithiums and alkyl halides, affords the corresponding ketones.
* Corresponding authors
a
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan
E-mail:
oshima@fm1.kuic.kyoto-u.ac.jp;
Fax: +81 75 753 4863;
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The oxidation of gem-disilylalkanes, which can be derived from 1,1-disilylethene, alkyllithiums and alkyl halides, affords the corresponding ketones.
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A. Inoue, J. Kondo, H. Shinokubo and K. Oshima, Chem. Commun., 2002, 114 DOI: 10.1039/B109656G
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