Issue 2, 2002

The d2/d3 alkyne redox pair [WF2(PhC[triple bond, length as m-dash]CPh)Tp′]z (z = +1 or 0): missing links in a ‘redox family tree’

Abstract

The d2/d3 redox pair [WF2(PhC[triple bond, length as m-dash]CPh)Tp′]z [z = +1 or 0, Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate] is the missing link in a ‘redox family tree’ relating the d6 tricarbonyls [M(CO)3L] to the d2 trihalides [MX3L] (M = Mo or W, L = Cp or Tp′) by a series of stepwise reactions involving sequential one-electron oxidation followed by ligand substitution.

Graphical abstract: The d2/d3 alkyne redox pair [WF2(PhC [[triple bond, length as m-dash]] CPh)Tp′] (z = +1 or 0): missing links in a ‘redox family tree’

Supplementary files

Article information

Article type
Communication
Submitted
18 Oct 2001
Accepted
22 Nov 2001
First published
20 Dec 2001

Chem. Commun., 2002, 130-131

The d2/d3 alkyne redox pair [WF2(PhC[triple bond, length as m-dash]CPh)Tp′]z (z = +1 or 0): missing links in a ‘redox family tree’

C. J. Adams, K. M. Anderson, N. G. Connelly, D. J. Harding, A. G. Orpen, E. Patron and P. H. Rieger, Chem. Commun., 2002, 130 DOI: 10.1039/B109535H

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