Issue 2, 2002
From the journal:

Chemical Communications

The d2/d3 alkyne redox pair [WF2(PhC[triple bond, length as m-dash]CPh)Tp′]z (z = +1 or 0): missing links in a ‘redox family tree’

Christopher J. Adams,a   Kirsty M. Anderson,a   Neil G. Connelly,*a   David J. Harding,a   A. Guy Orpen,a   Elena Patrona  and  Philip H. Riegerb  

* Corresponding authors

a School of Chemistry, University of Bristol, Bristol, UK
E-mail: Neil.Connelly@bristol.ac.uk

b Department of Chemistry, Brown University, Rhode Island, RI, USA

Abstract

The d2/d3 redox pair [WF2(PhC[triple bond, length as m-dash]CPh)Tp′]z [z = +1 or 0, Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate] is the missing link in a ‘redox family tree’ relating the d6 tricarbonyls [M(CO)3L]− to the d2 trihalides [MX3L] (M = Mo or W, L = Cp or Tp′) by a series of stepwise reactions involving sequential one-electron oxidation followed by ligand substitution.

Graphical abstract: The d2/d3 alkyne redox pair [WF2(PhC [[triple bond, length as m-dash]] CPh)Tp′] (z = +1 or 0): missing links in a ‘redox family tree’

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Article information

DOI
https://doi.org/10.1039/B109535H
Article type
Communication
Submitted
18 Oct 2001
Accepted
22 Nov 2001
First published
20 Dec 2001

Chem. Commun., 2002, 130-131

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The d2/d3 alkyne redox pair [WF2(PhC[triple bond, length as m-dash]CPh)Tp′]z (z = +1 or 0): missing links in a ‘redox family tree’

C. J. Adams, K. M. Anderson, N. G. Connelly, D. J. Harding, A. G. Orpen, E. Patron and P. H. Rieger, Chem. Commun., 2002, 130 DOI: 10.1039/B109535H

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