Issue 2, 2002
From the journal:

Chemical Communications

Amidation of silyl enol ethers and cholesteryl acetates with chiral ruthenium(ii) Schiff-base catalysts: catalytic and enantioselective studies†

Jiang-Lin Liang,ab   Xiao-Qi Yuab  and  Chi-Ming Che*ab  

* Corresponding authors

a Department of Chemistry and Open Laboratory of Chemical Biology of The Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong
E-mail: cmche@hku.hk

b Shanghai-Hong Kong Joint laboratory on Chemical Synthesis, Shanghai Institute of Organic Chemistry, Shanghai, China

Abstract

Chiral ruthenium(II)–salen complexes [RuII(salen)(PPh3)2] catalyse asymmetric aziridination of alkenes with up to 83% ees, asymmetric amidation of silyl enol ethers with up to 97% ees, and allylic amidation of cholesteryl acetates with good regioselectivity.

Graphical abstract: Amidation of silyl enol ethers and cholesteryl acetates with chiral ruthenium(ii) Schiff-base catalysts: catalytic and enantioselective studies

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B109272C
Article type
Communication
Submitted
16 Oct 2001
Accepted
31 Oct 2001
First published
09 Jan 2002

Chem. Commun., 2002, 124-125

Permissions

Request permissions

Amidation of silyl enol ethers and cholesteryl acetates with chiral ruthenium(II) Schiff-base catalysts: catalytic and enantioselective studies

J. Liang, X. Yu and C. Che, Chem. Commun., 2002, 124 DOI: 10.1039/B109272C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements