Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand
Abstract
The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C–H insertion into the
* Corresponding authors
a
Dyson Perrins Laboratory, South Parks Road, Oxford, UK
E-mail:
bjm@herald.ox.ac.uk
b
Dept. of Metal-Mediated Synthesis, Utrecht University, Padualaan 8, Utrecht, The Netherlands
E-mail:
g.vankoten@chem.uu.nl
The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C–H insertion into the
E. J. Farrington, E. Martinez Viviente, B. S. Williams, G. van Koten and J. M. Brown, Chem. Commun., 2002, 308 DOI: 10.1039/B108585A
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